A mononuclear cobalt(II) hydroxo complex: synthesis, molecular structure, and reactivity studies
نویسندگان
چکیده
منابع مشابه
Antiferromagnetic Coupling in a (/i-Hydroxo)(/x-pyrazolato)dicopper(II) Complex. Synthesis, Crystal Structure, Magnetic Properties, and Theoretical Studies
Binuclear Copper(II) Complex, Super-Exchange Interactions, Antiferromagnetic Coupling Preparation, crystal structure and magnetic properties of a 3,5-dimethylpyrazolate bridged binuclear copper(II) complex [Cu2(L')(3,5 prz)] (L1 = l,3-Bis(2-hydroxy-l-napthylideneamino)propan-2-ol) (1) are reported. Variable-temperature magnetic susceptibility measure ments for a powdered sample of the complex ...
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Terminal cobalt(IV)-oxo (CoIV-O) species have been implicated as key intermediates in various cobalt-mediated oxidation reactions. Herein we report the photocatalytic generation of a mononuclear non-haem [(13-TMC)CoIV(O)]2+ (2) by irradiating [CoII(13-TMC)(CF3SO3)]+ (1) in the presence of [RuII(bpy)3]2+, Na2S2O8, and water as an oxygen source. The intermediate 2 was also obtained by reacting 1 ...
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We report the first example of a mononuclear nonheme manganese(III)-hydroperoxo complex derived from protonation of an isolated manganese(III)-peroxo complex bearing an N-tetramethylated cyclam (TMC) ligand, [Mn(III)(TMC)(OOH)](2+). The Mn(III)-hydroperoxo intermediate is characterized with various spectroscopic methods as well as with density functional theory (DFT) calculations, showing the b...
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A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn(IV)=O adduct is capable of activating C-H bonds by a H-atom transfer mechanism and is more reactive in this regard than most Mn(IV)=O species.
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ژورنال
عنوان ژورنال: Transition Metal Chemistry
سال: 2008
ISSN: 0340-4285,1572-901X
DOI: 10.1007/s11243-008-9143-2